| 2016 | stage 3 | Granville - | Angers |  | Mark CAVENDISH | 223.5 km | 5:59:54 | 37.3 km/h | 19 |
| 2004 | stage 6 | Bonneval - | Angers |  | Tom BOONEN | 196.0 km | 4:33:41 | 43.0 km/h | 18 |
| 1979 | stage 5 | Neuville-de-Poitou - | Angers |  | Jan RAAS | 145.5 km | 3:38:00 | 40.8 km/h | 17 |
| 1977 | stage 7b | Angers - | Angers |  | Fiat | 4.0 km | 0:04:49 | 49.8 km/h | 16 |
| 1977 | stage 7a | Jaunay-Clan - | Angers | | Patrick SERCU | 139.5 km | 3:45:24 | 37.1 km/h | 15 |
| 1976 | stage 1 | Saint-Jean-de-Monts - | Angers | | Freddy MAERTENS | 173.0 km | 4:43:37 | 36.6 km/h | 14 |
| 1972 | stage P | Angers - | Angers | | Eddy MERCKX | 7.2 km | 0:08:51 | 48.8 km/h | 13 |
| 1970 | stage 3a | Angers - | Angers | | Faema-Faemino | 10.7 km | 0:13:25 | 47.9 km/h | 12 |
| 1970 | stage 2 | La Rochelle - | Angers | | Italo ZILIOLI | 200.0 km | 4:41:19 | 42.7 km/h | 11 |
| 1967 | stage 1a | Angers - | Angers |  | José-Maria ERRANDONEA | 5.8 km | 0:07:43 | 45.1 km/h | 10 |
| 1966 | stage 6 | Caen - | Angers | | Edward SELS | 216.5 km | 5:21:43 | 40.4 km/h | 9 |
| 1963 | stage 6b | Angers - | Angers |  | Jacques ANQUETIL | 24.5 km | 0:31:58 | 46.0 km/h | 8 |
| 1963 | stage 6a | Rennes - | Angers | | Roger DE BREUKER | 118.5 km | 2:44:05 | 43.3 km/h | 7 |
| 1960 | stage 7 | Lorient - | Angers | | Graziano BATTISTINI | 244.0 km | 6:00:24 | 40.6 km/h | 6 |
| 1956 | stage 7 | Lorient - | Angers | | Alessandro FANTINI | 244.0 km | 5:59:20 | 40.7 km/h | 5 |
| 1954 | stage 8 | Vannes - | Angers | | Fred DE BRUYNE | 190.0 km | 4:27:04 | 42.7 km/h | 4 |
| 1951 | stage 7 | La Guerche - | Angers |  | Hugo KOBLET | 85.0 km | 2:05:40 | 40.6 km/h | 3 |
| 1950 | stage 7 | Saint-Brieuc - | Angers | | Nello LAUREDI | 248.0 km | 6:43:05 | 36.9 km/h | 2 |
| 1936 | stage 19c | Cholet - | Angers | | Paul MAYE | 67.0 km | 1:38:30 | 40.8 km/h | 1 |